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- Title
Fabrication of a Hydrogen‐Bonded Organic Framework Membrane through Solution Processing for Pressure‐Regulated Gas Separation.
- Authors
Feng, Shou; Shang, Yanxue; Wang, Zhikun; Kang, Zixi; Wang, Rongming; Jiang, Jianzhuang; Fan, Lili; Fan, Weidong; Liu, Zhanning; Kong, Guodong; Feng, Yang; Hu, Songqing; Guo, Hailing; Sun, Daofeng
- Abstract
Ordered and flexible porous frameworks with solution processability are highly desirable to fabricate continuous and large‐scale membranes for the efficient gas separation. Herein, the first microporous hydrogen‐bonded organic framework (HOF) membrane has been fabricated by an optimized solution‐processing technique. The framework exhibits the superior stability because of the abundant hydrogen bonds and strong π–π interactions. Thanks to the flexible HOF structure, the membrane possesses the unprecedented pressure‐responsive H2/N2 separation performance. Furthermore, the scratched membrane can be healed by the treatment of solvent vapor, achieving the recovery of separation performance.
- Subjects
SEPARATION of gases; GAS separation membranes; FLEXIBLE structures; HYDROGEN bonding
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 10, p3868
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201914548