We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Selective Functionalization of Aromatic C(sp<sup>2</sup>)−H Bonds in the Presence of Benzylic C(sp<sup>3</sup>)−H Bonds by Electron-Deficient Carbenoids Generated from 4-Acyl-1-Sulfonyl-1,2,3-Triazoles.
- Authors
Miura, Tomoya; Zhao, Qiang; Murakami, Masahiro
- Abstract
A rhodium(II)-catalyzed reaction of newly prepared 4-acyl-1-sulfonyl-1,2,3-triazoles with benzene, and its derivatives, is investigated. Acceptor/acceptor carbenoids generated from 4-acyltriazoles undergo selective insertion at aromatic C(sp2)−H bonds in the presence of benzylic C(sp3)−H bonds to produce N-sulfonylenaminones.
- Subjects
TRANSITION metal carbenoids; RHODIUM catalysts; TRIAZOLE derivatives; BENZENE derivatives; AROMATIC compounds; CARBON-hydrogen bonds
- Publication
Angewandte Chemie, 2017, Vol 129, Issue 52, p16872
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201709384