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- Title
The Origin of Ultralow Thermal Conductivity in InTe: Lone-Pair-Induced Anharmonic Rattling.
- Authors
Jana, Manoj K.; Pal, Koushik; Waghmare, Umesh V.; Biswas, Kanishka
- Abstract
Understanding the origin of intrinsically low thermal conductivity is fundamentally important to the development of high-performance thermoelectric materials, which can convert waste-heat into electricity. Herein, we report an ultralow lattice thermal conductivity (ca. 0.4 W m−1 K−1) in mixed valent InTe (that is, In+In3+Te2), which exhibits an intrinsic bonding asymmetry with coexistent covalent and ionic substructures. The phonon dispersion of InTe exhibits, along with low-energy flat branches, weak instabilities associated with the rattling vibrations of In+ atoms along the columnar ionic substructure. These weakly unstable phonons originate from the 5s2 lone pair of the In+ atom and are strongly anharmonic, which scatter the heat-carrying acoustic phonons through strong anharmonic phonon-phonon interactions, as evident in anomalously high mode Grüneisen parameters. A maximum thermoelectric figure of merit ( z T) of about 0.9 is achieved at 600 K for the 0.3 mol % In-deficient sample, making InTe a promising material for mid-temperature thermoelectric applications.
- Subjects
THERMAL conductivity; COVALENT bonds; SUBSTRUCTURING techniques; PHONON dispersion relations; ACOUSTIC phonons; GRUNEISEN constant
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 27, p7923
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201511737