We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Efficient Synthesis, Structure, and Complexation Studies of Electron-Donating Thiacalix[ n]dithienothiophene.
- Authors
Inoue, Ryota; Hasegawa, Masashi; Nishinaga, Tohru; Yoza, Kenji; Mazaki, Yasuhiro
- Abstract
A series of thiacalix[n]dithiothiophenes (n=4-10) was prepared by a facile method and X-ray analysis was used to determine the molecular structures of square- (4-mer) and pentagonal-shaped macrocycles (5-mer). In the cyclic voltammograms, reversible multielectron redox processes, which are due to electronic delocalization, were observed at low oxidation potentials. The cyclic 4-mer acted as a 'Janus-head' cavitand for two C60 molecules, whereas the 5- and 6-mer formed stable 1:1 complexes with C60 .
- Subjects
ELECTRON donors; ELECTRON donor-acceptor complexes research; COMPLEXATION reactions; OXIDATION; OXIDATION-reduction reaction
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 9, p2772
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201410970