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- Title
Molecular and Crystal Structure of Octamethyl-1,4-dioxacyclohexasilane.
- Authors
Korlyukov, A. A.; Chernyavskaya, N. A.; Antipin, M. Yu.; Lysenko, K. A.; Chernyavskii, A. I.
- Abstract
Using X-ray diffraction, we have observed flattening of the six-membered ring in the octamethyl-1,4-dioxacyclohexasilane molecules. According to the results of a quantum-chemical calculation [B3LYP/6-311+G(d)], this flattening is due to the low barrier to hindered internal rotation about the Si-O bonds.
- Subjects
X-ray diffraction; OPTICAL diffraction; OPTICS; MOLECULAR rotation; STEREOCHEMISTRY; CHEMICAL bonds
- Publication
Chemistry of Heterocyclic Compounds, 2005, Vol 41, Issue 4, p536
- ISSN
0009-3122
- Publication type
Article
- DOI
10.1007/s10593-005-0183-7