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- Title
Photocatalytic Alkylation of α-(Trifluoromethyl)Styrenes with Potassium Xanthogenates.
- Authors
Supranovich, Vyacheslav I.; Dilman, Alexander D.
- Abstract
A protocol for the coupling of potassium xanthogenates with α-(trifluoromethyl)styrenes in the presence of triethyl phosphite is reported. The reaction is carried out under blue light irradiation in the presence of organic photocatalyst 3DPAFIPN. The reaction proceeds via formation of alkyl radicals from readily available xanthogenate salts via oxidative desulfurization and cleavage of the carbon–oxygen bond assisted by triethyl phosphite.
- Subjects
STYRENE; ALKYLATION; POTASSIUM; BLUE light; ALKYL radicals; SCISSION (Chemistry)
- Publication
Catalysts (2073-4344), 2021, Vol 11, Issue 12, p1555
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal11121555