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- Title
Diethylaluminum Iodide Promoted Morita-Baylis-Hillman Reaction of D-Glucose-Derived Densely O-Functionalized Cyclopentenone: Route to α-C-Branched Densely Functionalized Cyclic Enones.
- Authors
Ghosal, Partha; Ajay, Sama; Bajpai, Vikas; Kumar, Brijesh; Shaw, Arun K.
- Abstract
Morita-Baylis-Hillman (MBH) reaction of D-glucose-derived highly O-functionalized cyclopentenone is described for the first time. The MBH reaction of cyclopentenone with different aldehydes in the presence of diethylaluminum iodide proceeded smoothly in moderate to good yields. Promoters such as organic, inorganic, or Lewis bases and an aqueous medium are not suitable conditions for the MBH reaction of highly O-functionalized cyclopentenones with aldehydes.
- Publication
European Journal of Organic Chemistry, 2012, Vol 2012, Issue 26, p4906
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201200661