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- Title
Catalytic Enantioselective Allylation of Ketimines by Using Palladium Pincer Complexes with Chiral Bis(imidazoline)s.
- Authors
Nakamura, Shuichi; Hyodo, Kengo; Nakamura, Masayuki; Nakane, Daisuke; Masuda, Hideki
- Abstract
Get selective! Enantioselective allylation of ketimines derived from isatins by using chiral 1,3‐bis(imidazolin‐2‐yl)benzene (Phebim)–PdII complexes afforded products with good enantioselectivity (see scheme). The reaction was applied to a wide variety of ketimines. The obtained product can be converted to homoallylic amines and a spirocyclic amine without the loss of enantiopurity.
- Subjects
IMINES; ALLYLATION; ENANTIOSELECTIVE catalysis; FLUORIDES; ISATIN; AMINES
- Publication
Chemistry - A European Journal, 2013, Vol 19, Issue 23, p7304
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201300685