We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Homogeneous Catalytic Reduction of CO<sub>2</sub> with Silicon‐Hydrides, State of the Art.
- Authors
Fernández‐Alvarez, Francisco J.; Oro, Luis A.
- Abstract
During recent years, the catalytic transformation of CO2 using silicon‐hydrides as reductants has emerged as a promising methodology that allows the selective reduction of CO2 to the formate, formaldehyde, methoxide or methane level under mild reaction conditions. Moreover, some catalysts have been employed for the formylation and/or methylation of the N−H bonds of secondary and/or primary amines by their reaction with CO2 and hydrosilanes. This work summarizes the different catalytic systems that have shown to be efficient for the above‐mentioned reactions. Furthermore, a brief description of the reactions performance and the conditions employed in each case is included. From silicon valley to silicon hydrides: Catalytic reduction of CO2 with silicon‐hydrides could be considered as a promising and emerging chemical methodology.
- Subjects
CARBON dioxide; CATALYTIC reduction; SILICON; HYDRIDES; HOMOGENEOUS catalysis; FORMYLATION; METHYLATION; HYDROSILYLATION
- Publication
ChemCatChem, 2018, Vol 10, Issue 21, p4783
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.201800699