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- Title
Oligomerization of Unsaturated Compounds in the Presence of Amorphous Mesoporous Aluminosilicates.
- Authors
Bubennov, S. V.; Grigor'eva, N. G.; Serebrennikov, D. V.; Agliullin, M. R.; Kutepov, B. I.
- Abstract
High activity and selectivity of the samples of ASM amorphous mesoporous aluminosilicates in the synthesis of practically important oligomers of various unsaturated compounds (C5–C16 linear α-olefins, cyclooctene, norbornene, and α-methylstyrene) is found. The oligomerization products obtained in the presence of ASM have a broader molecular weight distribution in comparison with the oligomers synthesized over the H-Beta zeolite. The mesoporous structure of the ASM aluminosilicate provides the preparation of dimers of cyclooctene with high selectivity without cycle opening.
- Subjects
OLIGOMERS; UNSATURATED compounds; OLIGOMERIZATION; ALUMINUM silicates
- Publication
Petroleum Chemistry, 2019, Vol 59, Issue 7, p682
- ISSN
0965-5441
- Publication type
Article
- DOI
10.1134/S096554411907003X