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- Title
Synthesis, Structure, Photoluminescence, and Theoretical Calculation of an rtl-type Zinc(II) Compound with Linear Trinuclear [Zn<sub>3</sub>(COO)<sub>4</sub>(μ<sub>2</sub>-H<sub>2</sub>O)<sub>2</sub>] Subunits.
- Authors
Chen, Yan‐Xue; Tang, Kang‐Kang; Wang, Xin; Chen, Bing‐Yi; Qin, Guo‐Qiang; Yang, Jin‐Hui
- Abstract
The zinc(II) coordination polymer [Zn3(BPT)2(μ2-H2O)2(H2O)2] n · n(DMA) ( 1) (H3BPT = biphenyl-3,4′,5-tricarboxylic acid, DMA = N,N′-dimethylactamide) was obtained by the solvothermal reaction of H3BPT with Zn(NO3)2 in DMA/H2O mixed solvent. Single crystal X-ray analysis reveals that compound 1 has a complicated 3D framework containing linear trinuclear [Zn3(COO)4(μ2-H2O)2] clusters as building subunits, which can be simplified into a (3,6)-connected rtl topological network with the Schläfli symbol {4.62}2{42.610.83}. The calculated results of total and partial density of states (DOS) indicate that the luminescence of 1 mainly originates from intraligand charge transfer.
- Subjects
COORDINATION polymers synthesis; ZINC; DYNKIN diagrams; LUMINESCENCE; CHARGE transfer
- Publication
Zeitschrift für Anorganische und Allgemeine Chemie, 2014, Vol 640, Issue 11, p2292
- ISSN
0044-2313
- Publication type
Article
- DOI
10.1002/zaac.201400213