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- Title
Diverse Reactivity in a Rhodium(III)-Catalyzed Vinylic sp<sup>2</sup> C-H Bond Functionalization: Synthesis of Fused Polycyclic Heteroarenes or Conjugated Dienes.
- Authors
Li, Shuai ‐ Shuai; Xia, Ying ‐ Qi; Liu, Chen ‐ Fei; Zhang, Guo ‐ Tai; Su, Fu; Zhang, Xiao ‐ Mei; Dong, Lin
- Abstract
An efficient rhodium(III)-catalyzed vinylic sp2 C-H bond activation of 7-azaindoles with alkynes is reported, leading to the controlled synthesis of stereodefined diene and fused polycyclic heteroarene products. The novel strategy for the synthesis of diverse coupling products was controlled by the reaction conditions and the substitutions on the vinyl group.
- Subjects
DIOLEFINS; HETEROCYCLIC compounds; HETEROARENES; AROMATIC compounds; RHODIUM catalysts
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 23, p3724
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600666