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- Title
Mild Palladium-Catalyzed Oxidative Direct ortho-CH Acylation of Anilides under Aqueous Conditions.
- Authors
Szabó, Fruzsina; Daru, János; Simkó, Dániel; Nagy, Tibor Zs.; Stirling, András; Novák, Zoltán
- Abstract
Palladium-catalyzed cross-dehydrogenative coupling between anilides and aromatic aldehydes was achieved under aqueous conditions. A wide variety of the desired benzophenone derivatives was isolated in good to excellent yield. The reaction rate acceleration effect of acid and detergent has been demonstrated. Mechanistic insight has been obtained from quantum chemical calculations.
- Publication
Advanced Synthesis & Catalysis, 2013, Vol 355, Issue 4, p685
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201200948