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- Title
The Heptacyanotungstate(IV) Anion: A New 5 d Transition-Metal Member of the Rare Heptacyanometallate Family of Anions.
- Authors
Birk, Francisco J.; Pinkowicz, Dawid; Dunbar, Kim R.
- Abstract
The heptacyanotungstate(IV) anion was isolated in the salt ( n-Bu4N)3[WIV(CN)7] ( 1) from the reduction of (n-Bu4N)3[WV(CN)8] with concomitant loss of one cyanide ligand. The anion in 1 adopts a slightly distorted pentagonal bipyramidal geometry with an average W−C distance of 2.169 Å. The spectroscopic and magnetic properties are described.
- Subjects
CYANIDES; MAGNETIC properties; ANIONS; RADICAL anions; SOLVATED electrons; TRANSITION metals
- Publication
Angewandte Chemie International Edition, 2016, Vol 55, Issue 38, p11368
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201602949