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- Title
Intermolecular Hydroaminoalkylation of Propadiene.
- Authors
Kaper, Tobias; Fischer, Malte; Warsitz, Michael; Zimmering, René; Beckhaus, Ruediger; Doye, Sven
- Abstract
Intermolecular hydroaminoalkylation reactions of propadiene with selected secondary amines take place in the presence of a 2,6‐bis(phenylamino)pyridinato titanium catalyst. The corresponding products, synthetically useful allylamines, are formed in convincing yields and with high selectivities. In addition, propadiene easily inserts into the titanium‐carbon bond of a titanaaziridine.
- Subjects
ALLENE; TITANIUM catalysts; SECONDARY amines; ALLYLAMINES
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 63, p14300
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202003484