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- Title
Synthesis and Structural Study of Cytisinylphenylacetic Acid Nitriles.
- Authors
Ismailova, D. S.; Makhmudov, U. S.; Bobakulov, Kh. M.; Elmuradov, B. Zh.; Kadirov, A. A.; Shakhidoyatov, Kh. M.; Tashkhodzhaev, B.
- Abstract
Nitriles of stereoisomeric cytisinylarylacetic acids were synthesized by reacting cytisine with aromatic aldehydes in the presence of acetone cyanohydrin. Nitriles of cytisinylphenylacetic acids with the R- and S-configuration of the arylacetonitrile fragment were shown to be formed regioselectively in basic solution. The absolute configurations of the synthesized products were established using NMR spectroscopy and X-ray crystal structure analyses.
- Subjects
NITRILES; NUCLEAR magnetic resonance spectroscopy; X-ray spectroscopy; CRYSTAL structure; CYTISINE; AROMATIC aldehydes
- Publication
Chemistry of Natural Compounds, 2024, Vol 60, Issue 2, p291
- ISSN
0009-3130
- Publication type
Article
- DOI
10.1007/s10600-024-04305-7