We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Donor-Acceptor Shape Matching Drives Performance in Photovoltaics.
- Authors
Schiros, Theanne; Kladnik, Gregor; Prezzi, Deborah; Ferretti, Andrea; Olivieri, Giorgia; Cossaro, Albano; Floreano, Luca; Verdini, Alberto; Schenck, Christine; Cox, Marshall; Gorodetsky, Alon A.; Plunkett, Kyle; Delongchamp, Dean; Nuckolls, Colin; Morgante, Alberto; Cvetko, Dean; Kymissis, Ioannis
- Abstract
While the demonstrated power conversion efficiency of organic photovoltaics (OPVs) now exceeds 10%, new design rules are required to tailor interfaces at the molecular level for optimal exciton dissociation and charge transport in higher efficiency devices. We show that molecular shape-complementarity between donors and acceptors can drive performance in OPV devices. Using core hole clock (CHC) X-ray spectroscopy and density functional theory (DFT), we compare the electronic coupling, assembly, and charge transfer rates at the interface between C60 acceptors and flat- or contorted-hexabenzocorone (HBC) donors. The HBC donors have similar optoelectronic properties but differ in molecular contortion and shape matching to the fullerene acceptors. We show that shape-complementarity drives self-assembly of an intermixed morphology with a donor/acceptor (D/A) ball-and-socket interface, which enables faster electron transfer from HBC to C60. The supramolecular assembly and faster electron transfer rates in the shape complementary heterojunction lead to a larger active volume and enhanced exciton dissociation rate. This work provides fundamental mechanistic insights on the improved efficiency of organic photovoltaic devices that incorporate these concave/convex D/A materials.
- Publication
Advanced Energy Materials, 2013, Vol 3, Issue 7, p894
- ISSN
1614-6832
- Publication type
Article
- DOI
10.1002/aenm.201201125