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- Title
Synthesis and structural characterization of substituted phenols with a m-terphenyl backbone 2,4,6-R<sub>3</sub>C<sub>6</sub>H<sub>2</sub>OH (R=2,4,6-Me<sub>3</sub>C<sub>6</sub>H<sub>2</sub>, Me<sub>5</sub>C<sub>6</sub>).
- Authors
Şolea, Atena B.; Olaru, Marian; Silvestru, Cristian; Raţ, Ciprian I.
- Abstract
Substituted phenols with a m-terphenyl backbone 2,4,6-R3C6H2OH [R=2,4,6-Me3C6H2 (1), Me5C6 (2)] were synthesized using Kumada cross-coupling reactions between 2,4,6-I3C6H2OH and the corresponding Grignard reagent. Both compounds were structurally characterized in solution by 1H and 13C NMR spectroscopy and HRMS. The molecular structures of 1 and 2 were determined by single-crystal X-ray diffraction.
- Subjects
PHENOLS; TERPHENYL; GRIGNARD reagents; NUCLEAR magnetic resonance spectroscopy; X-ray diffraction
- Publication
Zeitschrift für Naturforschung B: A Journal of Chemical Sciences, 2015, Vol 70, Issue 1, p77
- ISSN
0932-0776
- Publication type
Article
- DOI
10.1515/znb-2014-0180