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- Title
Using sodium linoleate as a nucleating agent to improve the properties of PBAT/CaCO<sub>3</sub> composites.
- Authors
Sheng, Shuai; Li, Zhengxin; Li, Yinhong; Li, Yan; Zhong, Jin-Rong; Tan, Jinlin; Zhang, Yue-Fei
- Abstract
The purpose of this study is to investigate the use of nucleating agent to improve the overall performance of polybutylene adipate-co-terephthalate (PBAT) and calcium carbonate (CaCO3) composites. Specifically, sodium linoleate (Na-LL) is used as a chemical nucleating agent to improve the crystallization behavior of the material during melting extrusion processing. Mechanical, thermal, and morphological characteristics of PBAT and its composites were investigated. And a preliminary exploration was conducted on the mechanism of Na-LL improving the performance of PBAT. In this work, a formula has been obtained that dramatically saves production costs while improving product performance. After adding Na-LL to the composites, the thermal properties of the material were significantly improved, with a maximum crystallization temperature increase of 27.79 °C. In addition, composites offer superior mechanical properties compared to pure PBAT. When 0.2 parts by mass(pbw) Na-LL was added, the flexural modulus of the composites increased from 80.0 to 145.3 MPa, increased by 81.25%. The tensile performance can still be maintained at 11.0 Mpa, with elongation at break and impact strength reduced to 347.3% and 172.1 J/m, respectively. Under these conditions, it has excellent comprehensive mechanical properties. The results in this study suggest that Na-LL is a promising nucleating agent for enhancing the performance of composites and provides potential development of advanced materials for a wide range of applications in plastic packaging and plastic bags.
- Subjects
NUCLEATING agents; LINOLEIC acid; THERMOPHYSICAL properties; CALCIUM carbonate; PLASTICS in packaging; MELT spinning; FLEXURAL modulus
- Publication
Journal of Thermal Analysis & Calorimetry, 2023, Vol 148, Issue 24, p13859
- ISSN
1388-6150
- Publication type
Article
- DOI
10.1007/s10973-023-12584-5