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- Title
Electrochemical Intramolecular C—H/O—H Cross‐Coupling of 2‐Arylbenzoic Acids.
- Authors
Shao, Ailong; Li, Na; Gao, Yong; Zhan, Jirui; Chiang, Chien‐Wei; Lei, Aiwen
- Abstract
Abstract: A synthetic protocol to lactones by electro‐oxidative induced C—H activation of 2‐arylbenzoic acids has been developed. By using Na2SO4 aqueous solution as a cheap and green supporting electrolyte, different 2‐arylbenzoic acids could provide the corresponding lactones in 30%—90% yields. This reaction could be conducted on a gram scale with a good efficiency as well as a high utility for natural product synthesis.
- Subjects
INTRAMOLECULAR catalysis; AQUEOUS solutions; ELECTROLYTES; LACTONES; NATURAL products
- Publication
Chinese Journal of Chemistry, 2018, Vol 36, Issue 7, p619
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.201800031