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- Title
Synthesis, Structure and Properties of an Unusual 2D Network Zinc Coordination Polymer Based on Pentanuclear Zinc Cluster.
- Authors
Ding, Jiangang; Yin, Chao; Li, Ke; Li, Baolong; Wu, Bing
- Abstract
An unusual zinc(II) coordination polymer [Zn5(OH)2(bbtz)2(bdc)4] n ( 1) [bbtz1,4-bis(1,2,4-triazol-1-ylmethyl)benzene, bdc1,2-benzenedicarboxylate] was synthesized and characterized. 1 contains an unusual 2D network based on pentanuclear zinc(II) cluster [Zn5(OH)2]. Two adjacent pentanuclear Zn(II) clusters are bridged by four bdc ligands and extend to form the one-dimensional chain. The bbtz ligands further link the one-dimensional chains, resulting in a two-dimensional coordination network. The luminescence and thermal stability were investigated.
- Subjects
CLUSTER analysis (Statistics); ZINC compounds; LUMINESCENCE; COORDINATION polymers; TRIAZOLES; CARBOXYLATES
- Publication
Chinese Journal of Chemistry, 2014, Vol 32, Issue 7, p626
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.201400263