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- Title
A Novel Approach to Functionalization of Aryl Azides through the Generation and Reaction of Organolithium Species Bearing Masked Azides in Flow Microreactors.
- Authors
Ichinari, Daisuke; Ashikari, Yosuke; Mandai, Kyoko; Aizawa, Yoko; Yoshida, Jun‐ichi; Nagaki, Aiichiro
- Abstract
A novel straightforward method for aryl azides having functional groups based on generation and reactions of aryllithiums bearing a triazene group from polybromoarenes using flow microreactor systems was achieved. The present approach will serve as a powerful method in organolithium chemistry and open a new possibility in the synthesis of polyfunctional organic azides.
- Subjects
AZIDES; MICROREACTORS; ORGANIC synthesis; FUNCTIONAL groups; AZIDATION; SPECIES
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 4, p1583
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201912419