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- Title
Room temperature synthesis of cobalt-manganese-nickel oxalates micropolyhedrons for high-performance flexible electrochemical energy storage device.
- Authors
Zhang, Yi-Zhou; Zhao, Junhong; Xia, Jing; Wang, Lulu; Lai, Wen-Yong; Pang, Huan; Huang, Wei
- Abstract
Cobalt-manganese-nickel oxalates micropolyhedrons were successfully fabricated by a room temperature chemical co-precipitation method. Interestingly, the Co0.5Mn0.4Ni0.1C2O4*nH2O micropolyhedrons and graphene nanosheets have been successfully applied as the positive and negative electrode materials (a battery type Faradaic electrode and a capacitive electrode, respectively) for flexible solid-state asymmetric supercapacitors. More importantly, the as-assembled device achieved a maximum energy density of 0.46 mWh·cm−3, a decent result among devices with similar structures. The as-assembled device showed good flexibility, functioning well under both normal and bent conditions (0°-180°). The resulting device showed little performance decay even after 6000 cycles, which rendered the Co0.5Mn0.4Ni0.1C2O4*nH2O//Graphene device configuration a promising candidate for high-performance flexible solid-state asymmetric supercapacitors in the field of high-energy-density energy storage devices.
- Subjects
OXALATES; ENERGY storage; PRECIPITATION (Chemistry); GRAPHENE; ELECTRODES; ENERGY density
- Publication
Scientific Reports, 2015, p8536
- ISSN
2045-2322
- Publication type
Article
- DOI
10.1038/srep08536