We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Modulating Charge Transport from Thermally Activated to "Band‐Like" Through Interfacial Bottom‐Up Binding Capability of Bilayer Polymer Dielectrics.
- Authors
Zheng, Yingshuang; Lin, Hongzhen; Jiang, Ting; Zhu, Dongyang; Qi, Shengli; Li, Wei; Li, Liqiang; Ji, Deyang; Hu, Wenping
- Abstract
The disordered chain arrangement of polymer dielectrics has complex both internal and external effects on system performance, which generally stimulates the weak acquisition and grain boundaries of vapor‐deposited organic small molecule films (VDOSMFs) with thermally activated charge transport. As a result, achieving "band‐like" transmission of VDOSMs on polymer dielectrics is attempting to prove to be a major challenge. Three types of bi‐polymer dielectrics are developed to modulate charge transport from thermally activated mode to "band‐like" transport at the interfacial level. The bottom consisting of a polyimide layer is critical to interfacial modulation, which shows the selectively binding capability with up‐dielectric layers to realize the modulation of charge transport, as corroborated by interface characterization and density functional‐based tight‐binding calculation. The findings provide an effective strategy for modulating the charge transport through polymer dielectric engineering and also recommend a podium to further comprehend the electrical characteristics of small molecules in organic thin‐film transistors.
- Subjects
DIELECTRICS; POLYIMIDES; SMALL molecules; CRYSTAL grain boundaries; ORGANIC semiconductors; TRANSISTORS; POLYMERS; INDIUM gallium zinc oxide
- Publication
Advanced Functional Materials, 2023, Vol 33, Issue 10, p1
- ISSN
1616-301X
- Publication type
Article
- DOI
10.1002/adfm.202211742