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- Title
Rare Metal-Free Photo-Aerobic Intramolecular Dehydrogenative Cyclization Reaction towards Polycyclic Heteroarenes.
- Authors
Yamaguchi, Eiji; Sudo, Yusuke; Tada, Norihiro; Itoh, Akichika
- Abstract
We have achieved a rare-metal-free photo-aerobic intramolecular dehydrogenative coupling reaction from two C-H bonds of indole with malonate. This catalytic system proceeded at room temperature under visible light irradiation with oxygen in the air as a terminal oxidant, and the cyclization products were obtained in good to excellent yields.
- Subjects
CARBON-hydrogen bonds; RING formation (Chemistry); NONFERROUS metals; FREE radical reactions; PHOTOCHEMISTRY; INDOLE; MALONATES
- Publication
Advanced Synthesis & Catalysis, 2016, Vol 358, Issue 20, p3191
- ISSN
1615-4150
- Publication type
Article
- DOI
10.1002/adsc.201600291