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- Title
From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities.
- Authors
Corral-Bautista, Francisco; Klier, Lydia; Knochel, Paul; Mayr, Herbert
- Abstract
The influence of the metal on the nucleophilic reactivities of indenyl metal compounds was quantitatively determined by kinetic investigations of their reactions with benzhydrylium ions (Ar2CH+) and structurally related quinone methides. With the correlation equation log k2= sN( N+ E), it can be derived that the ionic indenyl alkali compounds are 1018 to 1024 times more reactive (depending on the reference electrophile) than the corresponding indenyltrimethylsilane.
- Subjects
CARBANIONS; ORGANOMETALLIC compounds; METAL ions; NUCLEOPHILIC reactions; QUINONE methides; ELECTROPHILES
- Publication
Angewandte Chemie International Edition, 2015, Vol 54, Issue 42, p12497
- ISSN
1433-7851
- Publication type
Article
- DOI
10.1002/anie.201501385