We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Corrigendum: Rhodium(III) Complex with a Bulky Cyclopentadienyl Ligand as a Catalyst for Regioselective Synthesis of Dihydroisoquinolones through C−H Activation of Arylhydroxamic Acids.
- Authors
Trifonova, Evgeniya A.; Ankudinov, Nikita M.; Kozlov, Maxim V.; Sharipov, Mikhail Y.; Nelyubina, Yulia V.; Perekalin, Dmitry S.
- Abstract
In the original article, Scheme 5 describes the reaction of O-Boc-phenylhydroxamic acid with a mixture of alkenes, Scheme 6 describes the reaction of O-Boc- and O-Piv-phenylhydroxamic acid with styrene. For example, reaction of B 1 a b with an equimolar mixture of allyl alcohol, styrene and myrcene proceed selectively in the presence of the catalyst B 5 b to give 4-CH SB 2 sb OH-substituted product B 4 e b in 89 % yield (Scheme 5). Indeed, we observed that the reaction of O-Boc-phenylhydroxamic acid B 1 a b with styrene in the presence of the classical catalyst [Cp*RhCl SB 2 sb ] SB 2 sb gives only the 3-benzylisoindolin-1-one B 4 p b , while similar reaction of O-pivaloyl-phenylhydroxamic acid B 1 b b produced the 3-substituted structural isomer B 3 p b (Scheme 6).
- Subjects
RHODIUM compounds; CATALYST synthesis; RHODIUM catalysts; RHODIUM; ACIDS; CHEMOSELECTIVITY; ALLYL alcohol
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 9, p3184
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.202003068