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- Title
CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties.
- Authors
Artem'ev, A. V.; Rakhmanova, M. I.; Samsonenko, D. G.
- Abstract
2-Ehtylthiopyridine (L) reacts with CuI (MeCN, r.t.) to afford a 1D chain coordination polymer (CP), [Cu2I2(L)]n in a 75% yield. The latter consists of double-stranded (Cu2I2)n ribbons ligated on both sides by 2-ehtylthiopyridines in a 1,3-N,S bridging manner. In the solid state at 298 K, this CP displays yellow-green photoluminescence (λmax = 550 nm) with a short lifetime (2.4 µs) and a moderate emission quantum yield (16%).
- Subjects
COORDINATION polymers; SULFIDE synthesis; PHOTOLUMINESCENCE
- Publication
Journal of Structural Chemistry, 2019, Vol 60, Issue 4, p617
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1134/S0022476619040127