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- Title
Unusual molecular structure of (C=O→Si←O′=C′) bis(2-methyl-4-pyrone-3-oxy)difluoro(λ<sup>6</sup>)siliconium.
- Authors
Voronkov, M. G.; Korlyukov, A. A.; Zel'bst, È. A.; Grebneva, E. A.; Trofimova, O. M.; Antipin, M. Yu.
- Abstract
X-ray diffraction is used to determine the crystal and molecular structure of spirocyclic (C=O→Si←O′=C′) bis(2-methyl-4-pyrone-3-oxy)difluoro(λ6)siliconium containing a hypervalent silicon atom and the previously unknown F2SiO4 coordination center. The coordination polyhedron of the silicon atom is a slightly distorted octahedron.
- Subjects
SILICON; MOLECULAR structure; CRYSTALS; ATOMS; CHEMICAL structure
- Publication
Journal of Structural Chemistry, 2009, Vol 50, Issue 6, p1204
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-009-0180-2