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- Title
Volatility and crystal lattice energy of palladium(II) chelates.
- Authors
Zharkova, G.; Stabnikov, P.; Sysoev, S.; Igumenov, I.
- Abstract
Temperature dependence of saturated vapor pressure has been measured by gas saturation technique for volatile bis-chelates of palladium(II) with such ligands as acetylacetone, hexafluoroacetylacetone, diethyldithiocarbamate, diisopropyldithiophosphate, and also mixed ligand complex with acetylacetone and cyclooctadiene-2,4. Standard thermodynamic parameters of vaporization Δ H and Δ S were calculated. Crystal molecular packings and intermolecular interactions were analyzed basing on structural data. Atomatom potential calculation of van der Waals energy E cryst in crystal lattice was performed and compared to the experimentally obtained values of sublimation enthalpy for the complexes under study.
- Subjects
TEMPERATURE; SATURATION vapor pressure; PALLADIUM; LIGANDS (Chemistry); VAN der Waals forces
- Publication
Journal of Structural Chemistry, 2005, Vol 46, Issue 2, p320
- ISSN
0022-4766
- Publication type
Article
- DOI
10.1007/s10947-006-0047-8