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- Title
Crystallographic Studies of Synthetic Corrinoids IV. Molecular Structure of a Ni(II)Oxa-porphyrinoid from Electrochemical Oxidation of a Ni(II) Seco-Corrin.
- Authors
Hodgson, Keith O.; Dunitz, Jack D.
- Abstract
X-ray analysis of a crystalline product obtained by electrochemical oxidation of the Ni(II)-seco-corrinoid 1 has established the structure as that of a 1,19 oxygen-bridged porphyrinoid 2. The crystals (perchlorate salt of 2) are triclinic, space group P 1, with a = 10.205, b = 11.616, c = 14.52Å, α = 115.30, β = 107.34, γ = 85.90°, Z = 2. The structure was solved by the heavy-atom method and refined by full-matrix least-squares analysis to a final R factor of 9.4%. Some features of the molecular structure are discussed.
- Publication
Helvetica Chimica Acta, 1976, Vol 59, Issue 5, p1898
- ISSN
0018-019X
- Publication type
Article
- DOI
10.1002/hlca.19760590547