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- Title
Click Chemistry as a Convenient Tool for the Incorporation of a Ruthenium Chromophore and a Nickel-Salen Monomer into a Visible-Light-Active Assembly.
- Authors
Herrero, Christian; Batchelor, Luke; Baron, Aurélie; El Ghachtouli, Sanae; Sheth, Sujitraj; Guillot, Régis; Vauzeilles, Boris; Sircoglou, Marie; Mallah, Talal; Leibl, Winfried; Aukauloo, Ally
- Abstract
Click chemistry was used to assemble a trimetallic RuII-NiII-RuII complex made up of two tris(bipyridyl)ruthenium(II)-based photosensitisers and a nickel(II)-salen complex. The electrochemical and photophysical properties of the resulting photosensitiser-metal complex are discussed. Photoinduced activation triggered by visible light absorption induces a fast intramolecular charge shift from one of the chromophores to the salen cavity to generate a nickel(III)-salen species.
- Subjects
NICKEL; RUTHENIUM; CHROMOPHORES; INORGANIC chemistry; PHOTOSENSITIVITY
- Publication
European Journal of Inorganic Chemistry, 2013, Vol 2013, Issue 4, p494
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201201161