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- Title
Thiomethylation of heteroaromatic amines.
- Authors
Akhmetova, V. R.; Niatshina, Z. T.; Starikova, Z. A.; Korzhova, L. F.; Ibragimov, A. G.
- Abstract
Thiomethylation of heteroaromatic amines with formaldehyde-hydrogen sulfide gave linear and cyclic heteroatom compounds: N,N′-[methylenebis(sulfanediylmethylene)]bishetarenamines and 5-hetaryl-1,3,5-dithiazinanes. N,N′-[Methylenebis(sulfanediylmethylene)]bishetarenamines were found to undergo transformation into 5-hetaryl-1,3,5-dithiazinanes by the action of CHO-HS. Transamination of 5-methyl-1 Hpyrazol-3-amine, 6-nitro-1,3-benzothiazol-2-amine, and 5-bromopyridin-2-amine with 5-methyl-1,3,5-dithiazinane selectively afforded the corresponding 5-hetaryl-1,3,5-dithiazinanes.
- Subjects
AMINES; HYDROGEN sulfide; ATOMS; NUCLEAR physics; ORGANIC chemistry
- Publication
Russian Journal of Organic Chemistry, 2011, Vol 47, Issue 6, p920
- ISSN
1070-4280
- Publication type
Article
- DOI
10.1134/S1070428011060157