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- Title
Concise synthesis of heliolactone, a non-canonical strigolactone isolated from sunflower.
- Authors
Yamamoto, Shunya; Atarashi, Taiki; Kuse, Masaki; Sugimoto, Yukihiro; Takikawa, Hirosato
- Abstract
Heliolactone is one of the earliest identified non-canonical strigolactones. Its concise synthesis was achieved by employing Knoevenagel-type condensation and semi-reduction of a malonate intermediate as the key steps. This synthesis was performed in a non-stereoselective manner, and thus a racemic and diastereomeric mixture of heliolactone was obtained. The developed synthetic route is fairly concise and straightforward. Graphical abstract A racemic and diastereomeric mixture of heliolactone was synthesized.
- Subjects
RACEMIC mixtures; STRIGOLACTONES; CONDENSATION; SAUSSUREA; SUNFLOWERS
- Publication
Bioscience, Biotechnology & Biochemistry, 2020, Vol 84, Issue 6, p1113
- ISSN
0916-8451
- Publication type
Article
- DOI
10.1080/09168451.2020.1734444