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- Title
Heat‐Treated Aerogel as a Catalyst for the Oxygen Reduction Reaction.
- Authors
Zion, Noam; Cullen, David A.; Zelenay, Piotr; Elbaz, Lior
- Abstract
Aerogels are fascinating materials that can be used for a wide range of applications, one of which is electrocatalysis of the important oxygen reduction reaction. In their inorganic form, aerogels can have ultrahigh catalytic site density, high surface area, and tunable physical properties and chemical structures—important features in heterogeneous catalysis. Herein, we report on the synthesis and electrocatalytic properties of an iron–porphyrin aerogel. 5,10,15,20‐(Tetra‐4‐aminophenyl)porphyrin (H2TAPP) and FeII were used as building blocks of the aerogel, which was later heat‐treated at 600 °C to enhance electronic conductivity and catalytic activity, while preserving its macrostructure. The resulting material has a very high concentration of atomically dispersed catalytic sites (9.7×1020 sites g−1) capable of catalyzing the oxygen reduction reaction in alkaline solution (Eonset=0.92 V vs. RHE, TOF=0.25 e− site−1 s−1 at 0.80 V vs. RHE).
- Subjects
OXYGEN reduction; CHEMICAL properties; ELECTROCATALYSIS; HETEROGENEOUS catalysis; ALKALINE solutions; CHEMICAL structure; CATALYTIC activity
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 6, p2504
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201913521