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- Title
Ligand‐Promoted Iron(III)‐Catalyzed Hydrofluorination of Alkenes.
- Authors
Xie, Yongtao; Sun, Peng‐Wei; Li, Yuxin; Wang, Siwei; Ye, Mengchun; Li, Zhengming
- Abstract
An iron‐catalyzed hydrofluorination of unactivated alkenes has been developed. The use of a multidentate ligand and the fluorination reagent N‐fluorobenzenesulfonimide (NFSI) proved to be critical for this reaction, which afforded various fluorinated compounds in up to 94 % yield.
- Subjects
IRON catalysts; ALKENES; FLUORINATION; SUPERACIDS
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 21, p7171
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201902607