We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
A Self‐Folding Polymer Film Based on Swelling Metal–Organic Frameworks.
- Authors
Troyano, Javier; Carné‐Sánchez, Arnau; Pérez‐Carvajal, Javier; León‐Reina, Laura; Imaz, Inhar; Cabeza, Aurelio; Maspoch, Daniel
- Abstract
Herein, we exploit the well‐known swelling behaviour of metal–organic frameworks (MOFs) to create a self‐folding polymer film. Namely, we show that incorporating crystals of the flexible MOF MIL‐88A into a polyvinylidene difluoride (PVDF) matrix affords a polymer composite film that undergoes reversible shape transformations upon exposure to polar solvents and vapours. Since the self‐folding properties of this film correlate directly with the swelling properties of the MIL‐88A crystals, it selectively bends to certain solvents and its degree of folding can be controlled by controlling the relative humidity. Moreover, it shows a shape‐memory effect at relative humidity values from 60 % to 90 %. As proof of concept, we demonstrate that these composite films can lift cargo and can be used to assemble 3D structures from 2D patterns. Our strategy is a straightforward method for designing autonomous soft materials with folding properties that can be tuned by judicious choice of the constituent flexible MOF.
- Subjects
POLYMER films; POLYVINYLIDENE fluoride; POLYMERS; POLAR solvents; HUMIDITY
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 47, p15646
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201808433