We found a match
Your institution may have rights to this item. Sign in to continue.
- Title
Cyclic Triradicals Composed of Iminonitroxide-Gold(I) with Intramolecular Ferromagnetic Interactions.
- Authors
Suzuki, Shuich; Wada, Tomoyuki; Tanimoto, Ryu; Kozaki, Masatoshi; Shiomi, Daisuke; Sugisaki, Kenji; Sato, Kazunobu; Takui, Takeji; Miyake, Yota; Hosokoshi, Yuko; Okada, Keiji
- Abstract
A triangular gold(iminonitroxide-2-ide) trimer complex ( 5) was prepared and investigated to determine its magnetic properties. The results showed that the metalloid triradical is highly stable, even in solution under aerated conditions. The intramolecular exchange interaction of 5 was found to be positive ( Jintra/ kB≈+29 K), thus showing that 5 is in a quartet ground state. In addition, a silver sandwich complex ( 5-Ag+- 5) was prepared and its electronic and magnetic properties were also clarified.
- Subjects
GOLD spectra; CLASS B metals; TRANSITION metals; MAGNETISM; TITANIUM group
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 36, p10949
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201604320