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- Title
PVDF-Based Fluoropolymer Modifications via Photoinduced Atom Transfer Radical Polymerizations.
- Authors
Xu, Nuo; Pan, Guangyu; Zhang, Hui; Lu, Peng; Shen, Lei; Li, Yuguang; Ji, Dong; Duan, Jindian; Hu, Xin; Lu, Chunhua; Xu, Zhongzi; Zhu, Ning; Guo, Kai
- Abstract
Graft modifications of PVDF fluoropolymers have been identified as the efficient route to improve the properties and expand the applications. Taking advantage of C-F and C-Cl bonds in the repeat units, atom transfer radical polymerizations (ATRP) were widely used for graft modification. Recently, photoinduced ATRP has shown good spatial and temporal control over the polymerization process in contrast to thermal activation mode. This minireview highlights the progress in PVDF-based fluoropolymer modifications by using photoinduced Cu(II)-mediated ATRP and organocatalyzed ATRP. The challenges and opportunities are proposed with the aim at advancing the development of synthesis and applications of fluoropolymer.
- Subjects
ATOMS; FLUOROPOLYMERS; POLYMERIZATION; LIVING polymerization
- Publication
Advances in Polymer Technology, 2022, Vol 2022, p1
- ISSN
0730-6679
- Publication type
Article
- DOI
10.1155/2022/7798967