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- Title
Sustainable Catalytic Synthesis of 2,5-Diformylfuran from Various Carbohydrates.
- Authors
Kim, Si Ae; Sung, Kihyuk; Jang, June Young; Bang, Sohee; Son, Seung Uk; Jang, Hye-Young
- Abstract
Versatile homogeneous and heterogeneous catalysts that convert carbohydrates to 2,5-diformylfuran (DFF) are essential for the development of sustainable processes for producing high-value chemicals from biomass-derived carbohydrates. An efficient catalytic system consisting of Br−, disulfide, and dimethylsulfoxide (DMSO) promoted the sustainable and selective synthesis of DFF in modest-to-good yields from various carbohydrates, such as fructose, glucose, mannose, galactose, and sucrose. Heterogeneous catalysts containing Br− also facilitated this reaction with recyclable high yields.
- Subjects
CARBOHYDRATES; BIOMASS chemicals; HETEROGENEOUS catalysts; GALACTOSE; SUSTAINABLE development; MANNOSE; FRUCTOSE
- Publication
Catalysts (2073-4344), 2022, Vol 12, Issue 4, p360
- ISSN
2073-4344
- Publication type
Article
- DOI
10.3390/catal12040360