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- Title
Sterically Controlled Diels-Alder Cycloadditions: Rapid Entry into the Illudin Scaffold.
- Authors
Stevens‐Cullinane, Lars; Lucas, Nigel T.; Hawkins, Bill C.
- Abstract
Rapid entry into the tricyclic ring system of the illudin family of natural products was achieved using a Diels-Alder cycloaddition of allylidenecyclopropane 7 and various cyclic and acyclic dienophiles. The reaction proceeds with complete regioselectivity and moderate to high stereoselectivity in good to excellent chemical yields.
- Subjects
RING formation (Chemistry); NATURAL products; DIENOPHILES; STEREOSELECTIVE reactions; REGIOSELECTIVITY (Chemistry)
- Publication
European Journal of Organic Chemistry, 2014, Vol 2014, Issue 22, p4767
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201402461