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- Title
Cesium Carbonate Mediated Borylation of Aryl Iodides with Diboron in Methanol.
- Authors
Zhang, Jieming; Wu, Hai‐Hong; Zhang, Junliang
- Abstract
Herein we describe the unexpected borylation of aryl iodides promoted by a Cs2CO3 and MeOH system. This formal nucleophilic boryl substitution could be applied to a wide range of functionalized aryl iodide compounds. The preliminary results indicate that this process is neither copper catalyzed nor radical mediated.
- Subjects
CESIUM compounds; ARYL iodides; METHANOL; NUCLEOPHILIC reactions; COPPER
- Publication
European Journal of Organic Chemistry, 2013, Vol 2013, Issue 28, p6263
- ISSN
1434-193X
- Publication type
Article
- DOI
10.1002/ejoc.201300829