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- Title
Small Molecules, Non-Covalent Interactions, and Confinement.
- Authors
Buntkowsky, Gerd; Vogel, Michael; Shenderovich, Ilya
- Abstract
This review gives an overview of current trends in the investigation of small guest molecules, confined in neat and functionalized mesoporous silica materials by a combination of solid-state NMR and relaxometry with other physico-chemical techniques. The reported guest molecules are water, small alcohols, and carbonic acids, small aromatic and heteroaromatic molecules, ionic liquids, and surfactants. They are taken as characteristic role-models, which are representatives for the typical classes of organic molecules. It is shown that this combination delivers unique insights into the structure, arrangement, dynamics, guest-host interactions, and the binding sites in these confined systems, and is probably the most powerful analytical technique to probe these systems.
- Subjects
SMALL molecules; MESOPOROUS materials; CARBONIC acid; BINDING sites; MESOPOROUS silica; MOLECULAR dynamics; IONIC surfactants
- Publication
Molecules, 2020, Vol 25, Issue 14, p3311
- ISSN
1420-3049
- Publication type
Article
- DOI
10.3390/molecules25143311