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- Title
The Effect of Ru Precursor and Support on the Hydrogenation of Aromatic Aldehydes/Ketones to Alcohols.
- Authors
Chaudhari, Chandan; Sato, Katsutoshi; Miyahara, Shin‐ichiro; Yamamoto, Tomokazu; Toriyama, Takaaki; Matsumura, Syo; Kusuda, Kohei; Kitagawa, Hiroshi; Nagaoka, Katsutoshi
- Abstract
Supported Ru catalysts were prepared by using different Ru precursors and examined for the hydrogenation of benzaldehyde to CHM. The catalyst prepared from Ru3(CO)12 precursor and HT support exhibited high yield of CHM. Moderate acidic and basic nature of HT was favourable to control the selectivity for CHM. The physicochemical properties analysis revealed that highly dispersed Ru nanoparticles were effective for the hydrogenation of benzaldehyde. RuCO/HT catalyst was tolerant to different functional groups and was stable until 7th cycle of recycle study.
- Subjects
RUTHENIUM catalysts; AROMATIC aldehydes; HYDROGENATION; KETONES; BENZALDEHYDE; HETEROGENEOUS catalysis; FUNCTIONAL groups
- Publication
ChemCatChem, 2022, Vol 14, Issue 16, p1
- ISSN
1867-3880
- Publication type
Article
- DOI
10.1002/cctc.202200241