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- Title
STUDY OF GRAFT SITES IN EPOXY GRAFT COPOLYMERS BY QUANTUM CHEMISTRY CALCULATIONS.
- Authors
Chen, Song; Li, Xiao-yu
- Abstract
Exploration and characterization of grafting productions by experimental methods are often cumbersome or sometimes impossible. Therefore, quantum chemistry calculations were performed to characterize the graft sites of epoxy resin. According to the Gibbs free energy criterion of the second law of thermodynamic, the reported graft sites were confirmed, and more important, some unreported graft sites were found. In addition, method of increasing the number of graft sites was studied in this article.
- Subjects
SURFACE grafting (Polymer chemistry); GRAFT copolymers; EPOXY resins; QUANTUM chemistry; THERMODYNAMICS
- Publication
Chinese Journal of Polymer Science (World Scientific Publishing Company), 2009, Vol 27, Issue 4, p517
- ISSN
0256-7679
- Publication type
Article
- DOI
10.1142/S0256767909004199