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- Title
Characteristics, seasonality and sources of inorganic ions and trace metals in North-east Asian aerosols.
- Authors
Pavuluri, Chandra Mouli; Kawamura, Kimitaka; Mihalopoulos, Nikolaos; Pingqing Fu
- Abstract
To better understand the characteristics, seasonality and sources of inorganic aerosols in North-east Asia, we studied total suspended particulate samples collected in Sapporo, northern Japan for inorganic ions and trace metals over a 1-year period. was found as the most abundant ionic species, which accounted for on average 43 ± 15% of the measured total ionic mass followed by . Among the metals determined, Ca was found as the most abundant (45 ± 5.2% of the measured total metals) followed by Fe. Temporal variations of methanesulfonate (MS-) and showed a clear seasonal pattern with a maximum in summer followed by spring. Cl-, , and K+ showed increasing trends from mid autumn to winter. Na+, Ca2+ and Mg2+ and crustal metals (Al, Ca, Fe, Ti and Mn) peaked in early spring. Na+ and Mg2+ and Ni, Cu and As were abundant in autumn whereas Zn was in spring. However, Cd and Pb did not show any seasonality. Based on comparisons of such seasonal trends with those of organic tracers as well as the air mass trajectories, we infer that the seasonality in inorganic aerosols in the North-east Asian atmosphere is mainly controlled by their season-specific source(s): soil dust in early spring, biogenic emissions in spring-summer, microbial activities in autumn and forest fires and biomass burning in autumn-winter. However, contributions from anthropogenic sources are significant in all seasons. This study also suggests that fungal spores partly contribute to some trace metals (i.e. Ni, Cu and As) whereas pollen contributes to Zn in aerosols.
- Publication
Environmental Chemistry (14482517), 2015, Vol 12, Issue 3, p338
- ISSN
1448-2517
- Publication type
Article
- DOI
10.1071/EN14186