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- Title
Nucleophilic Trifluoromethylthiolation of Alkyl Chlorides, Bromides and Tosylates.
- Authors
Xu, Chunfa; Chen, Qingyun; Shen, Qilong
- Abstract
A direct nucleophilic trifluoromethylthiolation of alkyl chlorides, bromides and tosylates with AgSCF3 was described. It was found that the presence of nBu4NI or a combination of nBu4NI/ nBu4NBr significantly enhanced the reaction rates. The reaction conditions were mild, thus allowing the tolerance of a variety of functional groups.
- Subjects
ALKYL chlorides; ALKYL compounds; CHLORIDES; BROMIDES; BROMINE compounds
- Publication
Chinese Journal of Chemistry, 2016, Vol 34, Issue 5, p495
- ISSN
1001-604X
- Publication type
Article
- DOI
10.1002/cjoc.201500905