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- Title
Cu<sup>II</sup> Complex of a 1,10‐Phenanthroline‐Based Pincer as an Efficient Catalyst for Oxidative Cross Dehydrogenative Coupling of Carboxylic Acids with Unactivated Alkanes.
- Authors
Jash, Upasona; Chakraborty, Gargi; Sinha, Suman; Sikari, Rina; Mondal, Rakesh; Paul, Nanda D.
- Abstract
Abstract: Synthesis of a well‐defined CuII complex 1 featuring a phenanthroline‐based tridentate scaffold, 2‐pyrazol‐(1,10‐phenanthroline) (L) and studies of its catalytic activity in the cross dehydrogenative coupling of acids with common alkanes to form allylic esters are reported. The complex 1 showed excellent catalytic activity in the oxidative cross dehydrogenative coupling of a wide variety of alkanes with acids to form the corresponding allylic esters in moderate to high yields. Several control experiments along with spectroscopic studies were carried out to characterize catalyst 1 and to explore the plausible mechanistic pathways.
- Subjects
PHENANTHROLINE derivatives; CARBOXYLIC acids analysis; ALKANE analysis; ALLYLIC alkylation; SPECTROSCOPIC imaging
- Publication
Asian Journal of Organic Chemistry, 2018, Vol 7, Issue 8, p1681
- ISSN
2193-5807
- Publication type
Article
- DOI
10.1002/ajoc.201800180