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- Title
Nickel acetylacetonate [Ni(acac)<sub>2</sub>] and montmorillonite K-10 promoted regioselective C-acylation of β-enamino compounds.
- Authors
Sheibani, Hassan; Seifi, Mohammad
- Abstract
Regioselective acylation of enaminones in the presence of catalysts such as nickel acetylacetonate [Ni(acac)2] and montmorillonite K-10 to give C-allylated products is reported. Nickel acetylacetonate [Ni(acac)2] complexes of β-enamino compounds react with electrophiles as phenyl isocyanate and isothiocyanate at methin carbon, in good to excellent yields.
- Subjects
MONTMORILLONITE; ACYLATION; CATALYSTS; ELECTROPHILES; ISOCYANATES; CARBYNES; ENAMINES; CHEMICAL inhibitors
- Publication
ARKIVOC: Online Journal of Organic Chemistry, 2009, p98
- ISSN
1551-7004
- Publication type
Article