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- Title
Synthesis of Elongated Esters from Alkenes.
- Authors
Miura, Tomoya; Funakoshi, Yuuta; Nakahashi, Junki; Moriyama, Daisuke; Murakami, Masahiro
- Abstract
A convenient method for synthesizing elongated aliphatic esters from alkenes is reported. An (alkoxycarbonyl)methyl radical species is generated upon visible‐light irradiation of an ester‐stabilized phosphorus ylide in the presence of a photoredox catalyst. This radical species adds onto the carbon–carbon double bond of an alkene to produce an elongated aliphatic ester.
- Subjects
ESTERS; ALKENES; METHYL radicals; IRRADIATION; PHOSPHORUS
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 47, p15681
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201809115